Webster is a kind man who happened to pick Adele up by the side of the road and offered to drive her into the city during his first appearance in Issue #433. When she accepted the lift, the two spent a longish drive into New York either making small talk or avoiding questions, and Webster became fixated on how mysterious Adele was wearing that black robe. He had no idea what she looked like under there but she really captured his curiosity.
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When Adele began to make it clear that she had unusual future-telling abilities, Webster took it surprisingly well and didn't seem particularly uncomfortable, and though he was disappointed that she did not want to show her face when they parted ways, they did end up keeping in touch. . . .
My favorite Webster pictures (click on the small pictures to see large, good quality scans):
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